Porous organic polymers with anchored aldehydes: a new platform for post-synthetic amine functionalization en route for enhanced CO2 adsorption properties

Porous organic polymers with anchored aldehydes: a new platform for post-synthetic amine functionalization en route for enhanced CO2 adsorption properties

Porous organic polymers with anchored aldehydes: a new platform for post-synthetic amine functionalization en route for
enhanced CO2 adsorption properties
V. Guillerm, Ł.J. Weseliński, M. Alkordi, M.I.H. Mohideen, Y. Belmabkhout, A.J. Cairns, and M. Eddaoudi
Chemical Communications 50, no. 16: 1937-40, (2014)
V. Guillerm, Ł.J. Weseliński, M. Alkordi, M.I.H. Mohideen, Y. Belmabkhout, A.J. Cairns, and M. Eddaoudi
Porous Organic Polymer, POP, PSM, Post-synthetic functionalization, Amine grafting, CO2 sorption, CO2 separation, Selectivity
2014
A novel porous organic polymer has been synthesized using the molecular building block approach to deliberately encompass aldehyde functionalities amenable to post functionalization. The resultant porous framework allows a facile, one-step quantitative and post-synthetic functionalization by amines, permitting enhanced CO2 sorption properties.












DOI: 10.1039/C3CC48228F