4-Connected Metal−Organic Assemblies Mediated via Heterochelation and Bridging of Single Metal Ions: Kagomé Lattice and the M6L12 Octahedron

by Liu Y., Kravtsov V.C., Beauchamp D.A., Eubank J.F., M. Eddaoudi
Year: 2005 DOI: 10.1021/ja051259q

Extra Information

J. Am. Chem. Soc., 2005, 127 (20), pp 7266–7267

Abstract

Single-metal-ion-based rigid molecular building blocks (MBBs) have been utilized to design and synthesize novel metal−organic assemblies. Reaction between In(NO3)3·2H2O and 2,5-pyridinedicarboxylic acid (2,5-H2PDC) has permitted the assembly of two supramolecular isomers, a Kagomé lattice and an unprecedented M6L12 discrete octahedron.
 

Keywords

MOF kagome heterochelation heterofunctional MOP octahedron