2012

Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material

Year: 2012 DOI:10.1021/ja209643b

Authors: Z. Zhang, L. Zhang, L. Wojtas, P. Nugent, M. Eddaoudi, M.J. Zaworotko

J. Am. Chem. Soc., 134 (2), pp. 924-927, (2012)

Metal exchange
Metal-organic
Microporous
Porphine
Templated synthesis
Cadmium chloride
Cadmium compounds
Carboxylation
Catalyst activity
Porphyrins
Synthesis (chemical)
Cadmium
Biphenyl 3
4'
5 tricarboxylate
Carboxylic acid derivative
Cation

Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins

Year: 2012 DOI:10.1021/ja208256u

Authors: Z. Zhang, L. Zhang, L. Wojtas, M. Eddaoudi, M.J. Zaworotko

J. Am. Chem. Soc., 134 (2), 928-933, (2012)

Heterogeneous catalyst
Metal-organic
Metalloporphyrins
Porphine
Resulting materials
Size-selective
Template-directed synthesis
Benzene
Manganese
Olefins
Porphyrins
Transition metals
Synthesis (chemical)
alkene derivative

Understanding hydrogen sorption in a polar metal-organic framework with constricted channels

Year: 2012 DOI:10.1063/1.3668138

Authors: A.C. Stern, J.L. Belof, M. Eddaoudi, B. Space

Journal of Chemical Physics, 136 (3), art. no. 034705, (2012)

Best choice
Close proximity
Electronic structure calculations
Energy interactions
Gas sorption
Gas sorption properties
Grand canonical Monte carlo
High fidelity
Hydrogen molecule
Hydrogen sorption
Isosteric heats
Metal Organic Framework

The unique rht-MOF platform, ideal for pinpointing the functionalization and CO2 adsorption

Year: 2012 DOI:10.1039/c1cc15962c

Authors: R. Luebke, J.F. Eubank, A.J. Cairns, Y. Belmabkhout, L. Wojtas, M. Eddaoudi

Chemical Communications, 48 (10), 1455-1457, (2012)

Carbon dioxide
Carboxylic acid derivative
Metal Organic Framework
Nitrogen
Adsorption
Article
Chemical structure
Adsorption
Carbon Dioxide
Ligands
Models
Molecular
Organometallic Compounds
Surface Properties

CO2 adsorption in mono-, di- and trivalent cation-exchanged metal-organic frameworks: A molecular simulation study

Year: 2012 DOI:10.1021/la205152f

Authors: Y.F. Chen, A. Nalaparaju, M. Eddaoudi, J.W. Jiang

Langmuir, 28 (8), 3903-3910, (2012)

Adsorption selectivity
Ambient conditions
Competitive adsorption
Henry's constants
Infinite dilution
Isosteric heats
Low pressures
Metal Organic Framework
molecular simulations
Nanoporous materials
Preferential adsorption
Saturation capacities

Efficient transfer hydrogenation reaction catalyzed by a dearomatized PN3P ruthenium pincer complex under base-free conditions

Year: 2012 DOI:10.1016/j.jorganchem.2011.10.017

Authors: L.P. He, T. Chen, D. Xue, M. Eddaoudi, K.W. Huang

Journal of Organometallic Chemistry, 700, 202-206, (2012)

Apical positions
CO ligands
Hydrogen transfer
Iso-propanols
Pincer
Pincer complexes
Pyridinic nitrogen
Square-pyramidal geometry
Transfer hydrogenations
Catalysis
Catalyst activity
Chlorine compounds
Formic acid
Hydrogen
Hydrogenation

Highly monodisperse M-III-based soc -MOFs (M = In and Ga) with cubic and truncated cubic morphologies

Year: 2012 DOI:10.1021/ja3049282

Authors: M. Pang, A.J. Cairns, Y. Liu, Y. Belmabkhout, H.C. Zeng, M. Eddaoudi

J. Am. Chem. Soc., 134 (32), 13176-13179, (2012)

Building blocks
Cubic morphology
Metal Organic Framework
Monodisperse
Morphological evolution
Self-assembled
Shape-controlled
Uniform crystals
Chemistry
Synthesis (chemical)
gallium
Indium
(111)

Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO2/CH4 selectivity

Year: 2012 DOI:10.1002/anie.201203594

Authors: Z. Zhang, W.Y. Gao, L. Wojtas, S. Ma, M. Eddaoudi, M.J. Zaworotko

Angewandte Chemie - International Edition, 51 (37), 9330-9334, (2012)

CO2/CH4 selectivity
Encapsulation
Anion binding
Cationic porphyrin
Inorganic salts
Metal Organic Framework
Metal salt
Metal-organic
Microporous
Open channels
Porphine
Porphyrinoids

On demand: the singular rht net, an ideal blueprint for the construction of a metal-organic framework (mof) platform

Year: 2012 DOI:10.1002/anie.201201202

Authors: J.F. Eubank, F. Nouar, R. Luebke, A.J. Cairns, L. Wojtas, M. Alkordi, T. Bousquet, M.R. Hight, J. Eckert, J.P. Embs, P.A. Georgiev, M. Eddaoudi

Angewandte Chemie - International Edition, 51 (40), 10099-10103, (2012)

Controlled porosity
Hybrid materials
Metal-organic frameworks
Reticular chemistry
Supermolecular building blocks
Building blocks
Metal Organic Framework
Crystal chemistry
Functional materials

Successful implementation of the stepwise layer-by-layer growth of MOF thin films on confined surfaces: Mesoporous silica foam as a first case study

Year: 2012 DOI:10.1039/c2cc36233c

Authors: O. Shekhah, J. Fu, R. Sougrat, Y. Belmabkhout, A.J. Cairns, E.P. Giannelis, M. Eddaoudi

Chemical Communications, 48 (93), 11434-11436, (2012)

Metal Organic Framework
Silicon dioxide
Article
crystal structure
Film
Porosity
Scanning electron microscopy
Surface property
Synthesis
X-ray diffraction

2012

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