Assembly of Metal–Organic Frameworks (MOFs) Based on Indium-Trimer Building Blocks: A Porous MOF with soc Topology and High Hydrogen Storage

by Liu Y., Eubank J.F., Cairns A.J., Eckert J., Kravtsov V.C., Luebke R., Eddaoudi M.
Year: 2007 DOI: 10.1002/anie.200604306

Extra Information

Angewandte Chemie International Edition Volume 46, Issue 18, pages 3278–3283, April 27, 2007

Abstract

The trimer building block [In3O(CO2)6] and a tetracarboxylate organic linker assemble into a novel porous metal–organic framework (see picture; In green, C gray, N blue, O red; cavity: yellow sphere) having an unprecedented soc topology (soc=square–octahedron) and high H2 uptake.

 

Keywords

Hydrogen storage Indium Metal–organic frameworks Molecular building blocks Porous materials