From metal-organic squares to porous zeolite-like supramolecular assemblie
byS. Wang, T. Zhao, G. Li, L. Wojtas, Q. Huo, M. Eddaoudi, Y. Liu
J. Am. Chem. Soc., 132 (51), 18038-18041, (2010)
We report the synthesis, structure, and characterization of two novel porous zeolite-like supramolecular assemblies, ZSA-1 and ZSA-2, having zeolite gis and rho topologies, respectively. The two compounds were assembled from functional metal-organic squares (MOSs) via directional hydrogen-bonding interactions and exhibited permanent microporosity and thermal stability up to 300 °C.