From metal-organic squares to porous zeolite-like supramolecular assemblie

by S. Wang, T. Zhao, G. Li, L. Wojtas, Q. Huo, M. Eddaoudi, Y. Liu
Year: 2010 DOI: 10.1021/ja109980c

Extra Information

J. Am. Chem. Soc., 132 (51), 18038-18041, (2010)


We report the synthesis, structure, and characterization of two novel porous zeolite-like supramolecular assemblies, ZSA-1 and ZSA-2, having zeolite gis and rho topologies, respectively. The two compounds were assembled from functional metal-organic squares (MOSs) via directional hydrogen-bonding interactions and exhibited permanent microporosity and thermal stability up to 300 °C.




Functional metals Hydrogen bonding interactions Metal-organic Supramolecular assemblies Thermal stability Hydrogen bonds Supramolecular chemistry Metal Organic Framework Unclassified drug Zeolite Zeolite-like supramolecular assembly