Structural diversity through ligand flexibility: two novel metal–organic nets via ligand-to-ligand cross-linking of “paddlewheels”

by W. Qiu, J.A. Perman, Ł. Wojtas, M. Eddaoudi, M.J. Zaworotko
Year: 2010 DOI: 10.1039/C0CC03270K

Extra Information

Chem. Commun., 46, 8734-8736, (2010)

Abstract

Solvothermal reaction of a partially flexible ligand, H4L, and Cu(NO3)2·2.5H2O afforded two cross-linked Kagomé lattices of formula [Cu2(L)]n: an acs net sustained by novel trigonal prismatic supermolecular building blocks (SBBs) and the first example of a partially pillared Kagomé net.
 

 

 

 

 

Keywords

MOF paddlewheel copper