Network diversity through decoration of trigonal-prismatic nodes: two-step crystal engineering of cationic metal-organic materials
byA. Schoedel, L. Wojtas, S.P. Kelley, R.D. Rogers, M. Eddaoudi, M.J. Zaworotko
Angewandte Chemie - International Edition, 50 (48), pp. 11421-11424, (2011)
MOMs the word! In a two-step process, first a trigonal-prismatic Primary Molecular Building Block ([Cr 3O(isonic) 6] +, tp-PMBB-1) was formed and then it was connected to linear linkers or square-planar nodes to afford three novel highly charged cationic metal-organic materials (MOMs) with snx, snw, and stp topologies.
ChromiumCrystal engineeringMesoporous materialsMetal-organic frameworksSynthesis designMesoporousMetal Organic FrameworkMetal-organicMolecular building blocksNetwork diversitySynthesis designTwo-step process