The asc trinodal platform: two-step assembly of triangular, tetrahedral, and trigonal-prismatic molecular building blocks

by A. Schoedel, A.J. Cairns, Y. Belmabkhout, L. Wojtas, M. Mohamed, Z. Zhang, D.M. Proserpio, M. Eddaoudi, M.J. Zaworotko
Year: 2013 DOI: 10.1002/anie.201206042

Extra Information

Angewandte Chemie-International Edition 52, no. 10: 2902-05, (2013)

Abstract


The self-assembly of triangular, tetrahedral, and trigonal-prismatic molecular building blocks affords the first example of a trinodal family of metal–organic materials. Four examples of isoreticular expanded and functionalized frameworks are detailed. Gas adsorption experiments validated the permanent porosity of the parent structure.
 

Keywords

Metal-organic frameworks MOFs