Revisiting the water sorption isotherm of MOF using electrical measurements

by S. Nandia, H. Aggarwal, M. Wahiduzzaman, Y. Belmabkhout, G. Maurin, M. Eddaoudi, S. Devautour-Vinot
Year: 2019 DOI: 10.1039/C9CC06012J

Extra Information

Chem. Commun., 2019, 55, 13251-13254


​Water adsorption/desorption isotherms of Cr-soc-MOF-1 were monitored electrically, with the translation of proton conductivity measurements to physisorption isotherms in terms of S-shape and hysteresis features revealed by volumetry. Molecular modelling further established the relationship between the evolutive water–hydrogen bonded network and the “electrical” isotherm for this water-mediated proton-conducting MOF.​


Water adsorption/desorption isotherms MOF waterhydrogen-bonded network electrical isotherm