Supermolecular building blocks (SBBs) for the design and synthesis of highly porous metal-organic frameworks

by Nouar F., Eubank J.F., Bousquet T., Wojtas L., Zaworotko M.J., M. Eddaoudi
Year: 2008 DOI: 10.1021/ja710123s

Extra Information

Journal of the American Chemical Society, 130 (6), 2008, 1833-1835


Here, we report a novel approach for the bottom-up assembly of hierarchical building blocks: simple molecular building blocks (MBBs) and the resultant supermolecular building blocks (SBBs) to build highly coordinated nets. A specific network, the (3,24)-connected rht, was used as a blueprint to construct a metal-organic framework where the MBBs/SBBs augment the net.


Copper Hydrogen Ligand metal metal organic polyhedra Nitrogen organic compound Unclassified drug Adsorption Article Chemical structure crystal structure desorption heating Porosity reaction analysis Structure analysis Synthesis X ray pow